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Beilstein J. Org. Chem. 2014, 10, 332–343, doi:10.3762/bjoc.10.31
Graphical Abstract
Figure 1: Structures of triads 1–6 and precursor molecules 7–8 used for the synthesis of the asymmetric syste...
Scheme 1: The one-step synthetic procedure towards the oxalate-bridged fullerene triads 4 and 6.
Scheme 2: Attempted synthetic pathway towards the formation of the C60–C70 oxalate bridged fullerene triad al...
Scheme 3: Synthetic pathway to the asymmetric fullerene triad 5 allowing introduction of the fullerene cages ...
Figure 2: Cyclic voltammograms of the terephthalate bridged triads 1–3 (left) and oxalate bridged triads 4–6 ...
Figure 3: Fluid solution EPR spectra recorded at 297 K for the two electron reduced species of compounds 1 an...
Figure 4: Frozen solution EPR spectra of triads 42− (a) and 12− (c), prepared by two electron reduction of 4 ...